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Side-functionalized two-dimensional polymers synthesized via on-surface Schiff-base coupling

  • 发布时间:2023-10-19
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  • 摘要:An imine-based 2D polymer side-functionalized with o-hydroxyl group was designed in regard to its potential ability to serve as a chelating agent and synthesized on a highly oriented pyrolytic graphite surface with a relatively low annealing temperature. When annealed to a higher temperature the o-hydroxyl group reacts further with the imine group, leading to the formation of oxazoline, which causes significant distortion to the network. The formation of oxazoline was further confirmed by ATR-FTIR.
  • 卷号:51
  • 期号:41
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